I am trying to download a program and every time I do my security system quarantines and removes the program when I try to unzip. It says it contains win32sdbot worm. Is there any way to remove the worm prior to unzipping so I can save the program.

Whats the program?
Where you trying to download it from?

I was trying to get an akvis file from Demonoid. Which I did and once I tried to unzip Mcafee would quarantine, tell me about the worm and later remove program.

A bittorrent site? My advice is, if you want it buy it. You can't seperate the worm from the RAR file, as in all honesty the RAR file probably contains nothing more than the worm. Sorry.